Abstract
Amongst the products formed when pyridine
reacts with benzoyl peroxide are phenylpyridines, benzoic acid, pyridine oxide,
and dipyridyls. The molar yield of benzoic acid is significantly higher than
that of the phenylpyridines although most aromatic compounds give approximately
equal yields of benzoic acid and phenylated compounds. This difference may be
ascribed to the simultaneous formation of pyridine oxide and dipyridyls.
Similar remarks apply to the reaction with quinoline and the mechanisms of the
various reactions are discussed.�The
phenylquinoline fraction has been investigated in detail and the isomer ratio
of the mixture has been evaluated.
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