Abstract
The ion-molecule reactions
of CH2F2 in the gas phase were studied using two mass
spectrometers, one fitted with a medium-pressure ion source and the other with
an ion-trap source. The main reaction was the formation of CH2F+
from CHF2+. The molecular ion and its proton transfer
reaction forming CH3F2+ were of lesser
importance. The only condensation ion formed was C2H4F3+.
Reaction cross sections and rate coefficients for a number of ions at exit
energies of 0.2-3.3 eV were measured.
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