Author:
Srinivasan VS,Sundaram AK
Abstract
The polarography of lead in the iodide
medium has shown that an irreversible wave is obtained at moderate
concentrations of lead, whereas at high concentrations two waves are obtained
and at low concentrations a single reversible wave is obtained. This explains
the irreversible waves obtained by the earlier workers who have mainly worked
in the region of 0.4mM of lead. From a study of the effect of the head of
mercury, temperature, etc. it is shown that the second wave is an adsorption
wave resulting from the adsorption of lead iodide complexes at the dropping
mercury electrode.
Cited by
9 articles.
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