The Structure of [PdCl2{(Py)2(PyH)CH-N′,N″}][PdCl4]0.5.2H2O (Py = Pyridin-2-yl), a Complex With Protonated 2,2′,2″-Methylidynetrispyridine as a Bidentate Ligand-Reference-Cited by-同舟云学术

The Structure of [PdCl2{(Py)2(PyH)CH-N′,N″}][PdCl4]0.5.2H2O (Py = Pyridin-2-yl), a Complex With Protonated 2,2′,2″-Methylidynetrispyridine as a Bidentate Ligand

Published:1992 Issue:2 Volume:45 Page:423
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Canty AJ,Minchin NJ,Skelton BW,White AH

Abstract

Crystals of dichloro[2,2′,2″-methylidynetris(pyridin)-1-ium-N′,N″]palladium(II) hemi[tetra-chloropalladate(II)] dihydrate are monoclinic, P21/c, a 8.558(5), b 15.516(7), c 16.153(5) a, P 112.07(4)°, Z 4. The cations [PdCl2{(Py)2(PyH)CH-N′,N″}]+ have square-planar geometry for palladium, with the ligand in a boat conformation and having an uncoordinated protonated pyridine group.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH9920423

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