Author:
Murray KS,Van den Bergen AM,West BO
Abstract
New salicylaldimine
chelates of divalent and trivalent ruthenium have been synthesized from RuCl2(PPh3)3.
The RuII complex trans- Ru(salen)(PPh3)2
is stable in the solid but very unstable to oxidation in solution. The RuIII derivative, Ru(salen)Cl(PPh3), displays
magnetic and e.s.r. properties consistent with a low-spin d5 system
under a ligand-field of rhombic symmetry.
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