Abstract
Aqueous solutions of
'mercurous nitrate' are shown by Raman spectra to contain the complexes [Hg2(OH2)NO3]+
and [Hg2(OH2)2]2+. Crystalline
dimercury(I) nitrate, Hg2(NO3)2,2H2O,
and its solid hydrolysis products Hg2(OH)2,3Hg2(NO3)2,
2Hg2(OH)2,3Hg2(NO3)2,H2O
and Hg2(OH)2,- Hg2(NO3)2
have been obtained: the vibrational spectra are reported and interpreted in
terms of possible structures. Modes v(Hg-Hg) appear in the range 170- 200 cm-1
and are sensitive to the particular combination of the ligands OH, ONO2,
and H2O attached to the dimercury(I) ion.
Cited by
11 articles.
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