Abstract
A description is given of
the chemistry which led to the synthesis of the title compound (1). Key
intermediate compounds in this synthetic route were tricyclo[5,3,1,04,9]undec-5-en-2-one
(13), tricyclo[5,3,1,04,9]undec-2-en-endo-6-ylmethanol (36) and the exo and endo isomers of chloroiceane (42) and
(44). Compound (42) must have a chlorine atom in the prow position of one of
the three rings in boat configurations.
Cited by
25 articles.
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1. Electronic Structure Calculations on Endohedral Complexes of Fullerenes: Reminiscences and Prospects;Molecules;2023-02-01
2. Inversion of configuration in modern synthesis;Addition, Elimination and Substitution: Markovnikov, Hofmann, Zaitsev and Walden;2022
3. Comparison of tri-, tetra- and pentacyclic caged hydrocarbons in Australian crude oils and condensates;Organic Geochemistry;2019-01
4. Dimerization of Pyramidalized 3,4,8,9-Tetramethyltetracyclo [4.4.0.03,9.04,8]dec-1(6)-ene to a Hydrocarbon Featuring Four Cyclohexane Rings in Boat Conformations;Angewandte Chemie International Edition;2014-06-16
5. Dimerization of Pyramidalized 3,4,8,9-Tetramethyltetracyclo [4.4.0.03,9.04,8]dec-1(6)-ene to a Hydrocarbon Featuring Four Cyclohexane Rings in Boat Conformations;Angewandte Chemie;2014-06-16