Metal template reactions. I. Benzilic acid rearrangement of 2,2'-pyridil and related compounds promoted by nickel(II) and cobalt (II) ions-Reference-Cited by-同舟云学术

Metal template reactions. I. Benzilic acid rearrangement of 2,2'-pyridil and related compounds promoted by nickel(II) and cobalt (II) ions

Published:1969 Issue:7 Volume:22 Page:1439
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Black DSC,Srivastava RC

Abstract

Reaction of 2,2?-pyridil with methanolic nickel(II) and cobalt(II) acetates results in the formation of metal complexes of 2,2?-pyridilic acid. This benzilic acid rearrangement is undergone similarly by 2,2?- quinaldil but not by benzil, 2,2?-furil, or I-phenyl-2-(2?- pyridyl)ethane-1,2-dione. Possible mechanisms for this rearrangement are discussed.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH9691439

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