On the Synthesis of 2,12-Dimethoxy-6,7,8,9-tetrahydro-5H-dibenz[d,f]azonine-3,11-diol and the Other Bridged Biphenyldiols and the E.S.R. of Their Oxidation Products in Relation to the Biosynthesis of Erythrina Alkaloids

Author:

Hewgill FR,Pass MC

Abstract

An improved synthesis in described for the dibenzazonine precursor of erysodienone . Other biphenyl-4,4′-diols, bridged by two, three and five atoms, were also prepared. E.s.r. examination of the oxidation of these compounds produced spectra of the 9,10-dihydrophenanthrene-4,4′- semiquinone system, hitherto unrecorded, but semiquinone spectra could not be obtained from the other diols.

Publisher

CSIRO Publishing

Subject

General Chemistry

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