Molecular susceptibility. The relative ring currents in pyridine, thiophen, furan, and pyrrole

Author:

Le Fevre RJW,Murthy DSN

Abstract

Molar Cotton-Mouton constants at infinite dilution in carbon tetrachloride are reported; from these, in conjunction with available polarizability and susceptibility data, the diamagnetic anisotropies of the solutes are evaluated. Using known molecular dimensions the π electron ring currents appear, relatively to benzene as 1, to be 1.06 : 0 .19 : 0.57 : 0.37 respectively for the four heterocycles in the title.

Publisher

CSIRO Publishing

Subject

General Chemistry

Cited by 23 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Physical Properties of Thiophene Derivatives;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

2. Part A. Properties and Reactions of Pyridines;Chemistry of Heterocyclic Compounds: A Series Of Monographs;2008-01-02

3. The structure of 6,6?-biquinolyl and its dication in solution;Russian Chemical Bulletin;1994-02

4. Cotton-mouton constants and valency optical scheme for salts of pyridine, quinoline, and isoquinoline;Bulletin of the Academy of Sciences of the USSR Division of Chemical Science;1991-03

5. Cotton-mouton constants and the magnetic anisotropy of pyridine, picolines, and lutidines;Bulletin of the Academy of Sciences of the USSR Division of Chemical Science;1990-04

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