Abstract
A comparison of Ep
reduction potentials with the absorption spectra and transition times of the
complexes has proved valuable in the investigation of the reduction of
nickel(II) complexes.
From the work it can be stated that as the
ligand in the complex becomes stronger (in the spectrochemical sense), the
complex becomes more stable towards the mercury drop in that higher negative
potentials are required for reduction and the chronopotentiometric
rate of reduction becomes greater.
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8 articles.
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