Author:
Harrowfield JM,Kepert DL,Patrick JM,White AH
Abstract
The crystal structures of
the nonahydrates of the rare earth trifluoromethanesulfonates, [M(OH2)9]
[CF3SO3]3 have been determined at 295 K for
the configurations fO, f7, f14,
i.e. M = La, Gd, Lu, together with that of the
yttrium analogue. The structures are similar to those of the rare earth ethyl
sulfate nonahydrates, belonging to space group P6,/m (hexagonal) with cell dimensions a ≈
13.7, c ≈ 7.5 �, Z 2, with the coordination about the rare earth atom
being a tricapped trigonal prism. The structure is
compared with that found from repulsion energy calculations.
Cited by
177 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献