Author:
Miller David J.,Moody Christopher J.,Morffitt C. Neil
Abstract
Rhodium(II)- or acid-mediated decomposition of 2-diazo-2-phenylacetates of
chiral alcohols in the presence of various hydroxylic compounds (ROH) results
in the diastereoselective formation of 2- hydroxy-, 2-alkoxy- or
2-trialkylsiloxy-2-phenylacetates, with the acid-mediated process giving the
higher diastereoselectivity.
Cited by
21 articles.
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