Author:
Cossey AL,Mander LN,Pyne SG
Abstract
7-Methyl-7,8-dihydro-4a,7-methano-4aH-benzocycloheptene-2,6(9H,5H-dione
(6) was prepared and reduced to a 3 : 7 mixture of the trans- and cis-decalin
derived ketones (8) and (15). Each compound was further elaborated to the
plant-growth-promoting acids (13), (14), (16) and (17). Dienone (5) was also
reduced (NaBH4, hydrogenation) to a 7 : 3 mixture of the cis- and trans-decalin derivatives (11) and (9). The stereochemistry of (11),
and by inference (12), was determined by correlation with the known ketone (7).
Cited by
11 articles.
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