Abstract
Halogeno complexes of
rhodium(III) of the type A2 [RhCl5H2O], A3
[RhCl6],H2O and A3 [Rh2X9]
(X = Cl, Br, A = alkali metal, ammonium and
alkylammonium cations) have been prepared and investigated structurally by
X-ray powder photography, and by infrared and visible spectroscopy. The
relationship between the various preparative procedures has been determined.
Factors such as acidity and type of cation are important. Structural and
spectroscopic studies have revealed trends which, in some cases, can be related
to the influence of the cations on the halogenorhodate(III) anions in the solid
state, and, in other cases, to the ionic/covalent nature of the metal-halogen
bond.
Cited by
26 articles.
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