Abstract
The development of the chemistry of benzyne and of arynes under flash vacuum pyrolytic conditions was strongly influenced by a parallel study of the chemistry of propadienones, and by the discovery of the acetylene/methylenecarbene rearrangement. A limited range of typical aryne reactions studied at The Australian National University and at Monash University from 1965 to 1996 is described, and pathways of aryne formation are considered.
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12 articles.
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