Abstract
The angular variation of
the e.s.r. g-value
of single crystals of CuSO4,5H2O has been measured in a number
of crystal planes. With the assumption that the resonances for each of two
independent tensors are symmetrically broadened, the data have been analysed to
obtain all the elements of these two tensors. The low value of X (1.27)
obtained for the fit to the data indicates that the values obtained for the
elements are of worthwhile accuracy. The orientations of the axes of the
tensorsin relationship to the Cu-O
bond vectors confirm assumptions made in previous treatments. The largest axis
of each tensor lies close to one of the Cu-O(SO3) bond directions.
Cited by
3 articles.
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1. Electron density in non-ideal metal complexes. I. Copper sulphate pentahydrate;Acta Crystallographica Section B Structural Science;1985-06-01
2. Copper;Coordination Chemistry Reviews;1983-12
3. Transition- metal ions;Electron Spin Resonance