Abstract
Internal pressures,
(∂U/∂V)T, have been obtained at 25� for the solvents dimethyl
sulphoxide, propylene carbonate, formamide, dimethylformamide, acetonitrile,
methanol and hexamethyl-phosphoramide by measurement
of the thermal pressure coefficients. Data in the literature suggest that
values of the internal pressure and the cohesive energy density, (ΔU/Vm),
are similar for a non-polar solvent. The observed divergence of the two
properties in the polar solvents under investigation is discussed in terms of
the nature of the solvent-solvent interactions.
Cited by
105 articles.
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