Abstract
The halides of Group I can be reduced to
metals in low-pressure electrical discharges produced in hydrogen, helium, and
nitrogen. Evidence is adduced to show that the active species are probably
electrons, and that the energy conditions of the electrons are reflected in the
effect of variation of gas pressure on the reduction rate. The effects of
surface area and dimerization of the halides, the gas pressure, and power are
also discussed, and the relationship between the reduction rate R and the power
input P is shown to be R = kP1.7, where k
is a constant.
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