Abstract
Heating myo-inositol
with an excess of the triethylammonium salt of N- benzoylphosphoramidic
acid in N,N-dimethylformamide results in phosphorylation of every hydroxyl
group. The method appears to be general for the complete phosphorylation of
unsubstituted or partially substituted inositols. Starting with 1-O-benzyl- and
4-O-benzyl-myo- inositol, phosphorylation and
subsequent hydrogenolysis gave DL-myo- inositol
1,2,4,5,6- and 1,2,3,4,5-pentaphosphate, respectively. Other methods of phosphorylation
were found unsuitable.
Cited by
15 articles.
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1. References;Chemistry of Plant Phosphorus Compounds;2013
2. Lower myo-Inositol Phosphates;Chemistry of Plant Phosphorus Compounds;2013
3. Phytic Acid;Chemistry of Plant Phosphorus Compounds;2013
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