Abstract
The chelating properties of
3-amino-I-(8?-quinolyl)-1-thiapropane (2) are discussed. The related ligands
1-(2?-hydroxyphenyl)-6-(8?- quinolyl)-5-thia-2-azapent-1-ene
(6), 1-(6?-bromo-2?-hydroxyphenyl)-5- (8?-quinolyl)-5-thia-2-azapent-1-ene
(7), 5-(2?-pyridyl)-1-(8?- quinolyl)-1-thia-4-azahex-4-ene
(8), and 5-[2?-(6?-acetylpyridyl)]-1- (8?-quinolyl)-1-thia-4-azahex-4-ene
(13), and some of their metal complexes are described. The iron(II) sexadentate
chelate (17) has been prepared by a metal template synthesis from the amine (2)
and glyoxal.
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