Author:
Cross JTD,Hunter R,Stimson VR
Abstract
Dimethyl carbonate does not
decompose at temperatures up to 390�. At 300-400� ethyl methyl, diethyl, ethyl
propyl and dipropyl carbonates yield carbon dioxide, the alkene and the alcohol
at similar rates with E (kJ mol-1) 182.0, 195.0, 181.6, 182.0 and
log A (s-1) 11.72, 13.06,
11.89, 11.97, respectively. With ethyl propyl carbonate, ethylene is the
slightly favoured alkene.
Cited by
46 articles.
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