A Corresponding States Treatment of the Speed of Sound in Simple Liquids

Author:

Hamann SD

Abstract

It is shown that the speed of sound in the simple liquids A, N2, O2, CH4 conforms to the principle of corresponding states as formulated by de Boer in molecular units. The lighter liquids H2 and He show negative deviations which are proportional to their quanta1 parameters Λ*. CCl4 shows a positive deviation which is most likely due to a difference in the form of its intermolecular potential from that of the other liquids. A simple theory is presented for the speed of sound in a hypothetical liquid at absolute zero. The calculated value is consistent with the experimental data at finite temperatures.

Publisher

CSIRO Publishing

Subject

General Chemistry

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