Dehydration Studies of r-4-Chloro-8a-methyl-trans- and cis-decahydronaphthalen-t-4a-ols-Reference-Cited by-同舟云学术

Dehydration Studies of r-4-Chloro-8a-methyl-trans- and cis-decahydronaphthalen-t-4a-ols

Published:1979 Issue:10 Volume:32 Page:2223
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Coxon JM,Gibson JR

Abstract

Electron-withdrawing substituents at C4 in 8a-methyl-trans-decahydronaphthalen-4a-ol allow methyl migration to compete with 1,2-elimination in H2SO4/HOAc/Ac2O media but not in SOCl2/ pyridine. Under both these reaction conditions for 4-substituted 8a-methyl-cis-decahydronaphthalen- 4a-ols methyl migration does not compete with 1,2-elimination.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH9792223

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