Solvent Exchange on (N,N-Diethylformamide)-[2,2',2'-Tri(Dimethylamino)Triethyl-Amine]Nickel (II)
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Published:1986
Issue:2
Volume:39
Page:367
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ISSN:0004-9425
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Container-title:Australian Journal of Chemistry
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language:en
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Short-container-title:Aust. J. Chem.
Author:
Lincoln SF,Coates JH,Doddridge BG,Hounslow AM
Abstract
A 1H n.m.r . study yields kex(298.2K) = 944�42s-1,
ΔH‡ = 23.1�0.7 kJ mol-1 and ΔS‡ = -111�2 JK-1 mol-1 for N,N- diethylformamide exchange [Ni(N(CH2CH2NMe2)3)-(OCHNEt2)]2+. These data are compared with those of related species.
Publisher
CSIRO Publishing
Subject
General Chemistry