Abstract
The proportion of the pyranose and furanose forms in
aqueous solutions of deoxyaldoses has been determined
by p.m.r. spectroscopy. Removal of a hydroxyl group
from C2 or C3 of an aldose causes an increase in the furanose content, particularly if the group was cis to another group. The strongest
unfavourable interaction in the furanose ring appears
to be the one between the side-chain and a neighbouring cis hydroxyl group.
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