Abstract
In the present study, a new type of material of Zr-TSCD was first synthesized and modified with different amounts of triethylenetetramine (TETA). The properties of the adsorbents were characterised with X-ray diffraction, UV-vis diffuse reflectance spectroscopy, FT-IR spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy, N2 adsorption–desorption, energy dispersion spectrum, and thermogravimetric analysis. The results suggested that Zr-TSCD (TSCD=Na3C6H5O7·2H2O) was successfully synthesized through the coordination of Zr atoms from ZrOCl2·8H2O and O species in –COO– groups. After functionalization with TETA, the structure of Zr-TSCD was preserved and the adsorption capacity of CO2 was enhanced dramatically. At 75°C, TETA(30)/Zr-TSCD achieved a maximum absorption capacity of 175.1mg g−1 in a stream of 10mL min−1 CO2. The adsorption capacity ratio of CO2/N2, CO2/O2, and CO2/SO2 was 10.5, 7.4, and 1.2, respectively. In addition, the adsorption capacity of CO2 remained stable during 10 adsorption–desorption cycles.