Abstract
The hyperfine coupling
constants for the radical anions of 2,3-dihydro-
phenalene (perinaphthane)
and 7,8,9,l0-tetrahydrocyclohepta[de]naphthalene have been determined from
analysis of the electron spin resonance spectra in solution. The results are
compared with data from other mono- and di-peri-
substituted naphthalenes. A simple H�ckel molecular orbital treatment is used
to describe the inductive effect of the aliphatic substituent.
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