Author:
Bell HC,Kalman JR,Pinhey JT,Sternhell S
Abstract
Syntheses of a number of
aryllead(IV) tricarboxylates are reported. Some of these compounds have been
prepared by the known methods of direct plumbylation, and reaction of a
diarylmercury compound with lead tetraacetate in a halogenated acetic acid. Two
further methods of preparation of aryllead tricarboxylates are reported and the
scope of each of these has been explored. The methods involve the reaction of
an arylmercury trifluoroacetate with lead tetrakistrifluoroacetatein trifluoroacetic acid,
and the reaction of aryltrimethylsilanes with lead tetraacetate in
trifluoroacetic acid.
Cited by
72 articles.
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