Photooxidation of 2-Phenylbenzotriazoles

Author:

Amiet RG,Evans NA,Wynne PM

Abstract

Irradiation, with ultraviolet light, of 2-phenylbenzotriazole in aerated solvents resulted in oxidation of the benzo ring to yield the diacid 2-phenyl-1,2,3-triazole-4,5-dicarboxylic acid. A possible intermediate, 2-phenylbenzotriazole-4,7-dione, also yielded the diacid on photooxidation . The methyl ether of the commercial photostabilizer Tinuvin P undergoes an analogous reaction to produce the corresponding diacid.

Publisher

CSIRO Publishing

Subject

General Chemistry

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Properties and Synthetic Utility of N-Substituted Benzotriazoles;Chemical Reviews;1998-01-30

2. Volume 4 References;Comprehensive Heterocyclic Chemistry II;1996

3. 1,2,3-Triazoles;Comprehensive Heterocyclic Chemistry II;1996

4. ESCA surface study of polystyrene photodegradation accelerated by 2-(2-methoxy-5-methylphenyl)-2H-benzotriazole;Macromolecular Rapid Communications;1995-11

5. Five-Membered Ring Systems: With More Than One N Atom;Progress in Heterocyclic Chemistry - A critical review of the 1989 literature preceded by one chapter on a current heterocyclic topic;1990

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