Author:
Kubo M,Kuroda M,Krishita M,Muto Y
Abstract
A new type of binuclear structure having
copper atoms of ligancy 4 is proposed on the basis of infrared C=O stretching
vibrations for the so-called three-coordinated copper(II) complexes showing a
normal magnetic moment. In this binuclear structure, copper atoms are bridged
in pairs by two Cu-O-C-O-Cu links of syn-anti arrangement. Suggestion is made
that "three-coordinated" copper(II) complexes in the literal sense of
the word do not exist regardless of whether the complexes show normal or
subnormal magnetic moments.
Cited by
36 articles.
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