Author:
Bowden JA,Colton R,Commons CJ
Abstract
The reactions of
triphenylphosphine and triphenylarsine with (π- arene)M(CO)3 (M
= Cr, Mo, W) to yield fac-M(CO)3(RPh3)3 (R =
P, As) have been reexamined. Anomalies in the earlier literature have been
resolved by the isolation of two solid state forms of each complex and by a
study of the decomposition products of these compounds. Tricarbonyl complexes
of tritolyl-phosphines and -arsines are also reported and their behaviour
suggests steric effects initiate decomposition. In addition, a number of
(π-arene)M(CO)3 compounds were shown to react with carbon
monoxide to form M(CO)6.
Cited by
11 articles.
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