Abstract
Norerythrostachaldine (1) and its naturally occurring 3β-acetate (2)
are highly cytotoxic aldehydic bases considered to be 19- oxonorcassaidine and
its 3β-acetate. The carbon skeleton, stereochemistry and position of
oxygen substituents were established by lithium aluminium hydride reduction of
(1) to give the tetrol (3) which was identical with a sample prepared from norerythrostachamine (4).
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