Abstract
Complexes of bi-and ter-valent technetium have been prepared with the
diphosphine 1,2-bis(diphenylphosphino)ethane,
viz. [Tc(diphos)2X2]
and [Tc(di-phos)2Br2]Br where X = CL, Br. The
complexes can be formulated as octahedral compounds and both magnetic and
spectral evidence agree with this. The quadrivalent
technetium compounds TcBr4, TcBr4(Ph3P)2,
and the salts (diphos-H2)TcX6 (X = CL, Br) and Ag2TcCl6 have also been prepared and
are described. Attempts to prepare the trichloride (TcCL3)
are also reported.
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