Author:
Snow MR,Pauling P,Stiddard MHB
Abstract
Substituted carbonyls of
the type (arene)M(CO)3 (M = Mo, W) react with iodine to yield
compounds containing the cation [(arene)M(CO)3I]+. X-ray
structure analysis shows the [(hexamethylbenzene)W(CO)3I]+
species to possess approximate Cs symmetry. It is unstable in
solution and reaction with bipyridyl and triphenyl-phosphine offers a new route
to derivatives of the type W(bipyridyl)2(CO)3I2
and W(PPh3)2(CO)3I2.
Cited by
25 articles.
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