Abstract
The circular dichroism
spectra are presented for the complexes, trans-[CoL2C12]+,
trans-[CoL2Br2]+,
[CoL(NH3)4]3+, [CoL(CN)4]-,
[MoL(CO)4] and [PtL(py)2]2+, where L is
(R)-1-phenylethane-l,2- diamine, in a number of solvents. The solvent
dependence of the spectra for the cobalt(m) complexes has been analysed in
terms of stereoselective solvation of the diamine N-H protons. The spectra are
compared with those of the analogous (R)-propane-1,2-diamine complexes. This
comparison shows that the so-called 'conformational effect' is not predominant.
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