Abstract
The Raman spectra of
solutions in acetone of crystalline salts with anionic stoicheiometries HgX3-, HgX42-,
Hg2X5-, and Hg3X82-
(where X = Cl, Br, or I) were determined. The
dominant species identified in all cases except (pyH)2HgI4 was HgX3-
which probably had a bent (C3v) configuration. The species Hg2I5- was also identified in
solutions of Me4NHg.2I5.
The disproportionation reactions are discussed in terms of ion-solvent
interactions.
Cited by
22 articles.
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