Structural Chemistry of [MX2(bipy)] (M=Pd, Pt; X=Cl, Br, I): the Yellow Polymorph of Dichlorido(2,2'-bipyridine)platinum(II) and Diiodido(2,2'-bipyridine)palladium(II), and Overview of this System-Reference-Cited by-同舟云学术

Structural Chemistry of [MX2(bipy)] (M=Pd, Pt; X=Cl, Br, I): the Yellow Polymorph of Dichlorido(2,2'-bipyridine)platinum(II) and Diiodido(2,2'-bipyridine)palladium(II), and Overview of this System

Published:2011 Issue:10 Volume:64 Page:1355
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Canty Allan J.,Gardiner Michael G.,Jones Roderick C.,Sharma Manab

Abstract

Synchrotron data have been used to determine the structures of the yellow polymorph of dichlorido(2,2′-bipyridine)platinum(ii) (1), and diiodido(2,2′-bipyridine)palladium(ii) (2), allowing a detailed comparison of the crystal chemistry of [MX2(bipy)] (M = Pd, Pt; X = Cl, Br, I), which exhibit polymorphism involving nine structures distributed over five space groups. Complex 1 crystallizes in space group Pbca (a = 18.2540(7), b = 15.6970(7), c = 7.3560(6) Å), and 2 in space group C2/c (a = 17.149(1), b = 9.8050(8), c = 7.548(1) Å, β = 110.72(1) °).

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH11095

Reference19 articles.

1. 201. Researches on residual affinity and co-ordination. Part XXXIV. 2 : 2′-Dipyridyl platinum salts

2. Spectroscopic studies on some compounds (including dimorphic solids) of platinum(II) with 2,2′-bipyridyl and its analogues

3. Crystal structure of the red form of 2,2′-bipyridyldichloroplatinum(II)

4. R�ntgenographische und spektroskopische Untersuchungen an zwei Modifikationen von Dichloro-2,2?-dipyridyl-platin(II)

5. Crystal Structure of(2,2'-Bipyridine)dichloropalladium(II).

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