Author:
Brown RFC,Eastwood FW,Lim ST,McMullen GL
Abstract
Thermal fragmentation of
5-acyloxy-1,3-dioxan-4,6-diones (4) or thermal α-elimination of benzoic acid
from the benzoyloxylactones (14) and (15) leads to
1,2-diketones in high yield. It is proposed that these 1,2-diketones are
products of the rearrangement of transient intermediates which are formulated
as acyloxycarbenes.
Cited by
30 articles.
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