Author:
Coutts RSP,Wailes PC,Kingston JV
Abstract
The first xanthates of titanium have been prepared from cp2TiCl (cp = π-cyclo-pentadienyl)
and NaS2COR (R = CH3, C2H2,
n-C3H7, n-C4H9, and n-C5H11)
in air-free water under inert atmosphere. The trivalent titanium complexes are
blue in colour, monomeric, and extremely sensitive to
oxygen, with one unpaired electron per titanium atom. They are believed to be
of the form
(See diagram in article)
with bidentate xanthato ligands, analogous to the corresponding dithiocarbamates.
Cited by
17 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献