Author:
Coutts RSP,Wailes PC,Kingston JV
Abstract
Several N,N-dialkyldithiocarbamates
of bis(cyclopentadienyl)titanium(111) have been
prepared from cp2TiCl (cp = π-cyclopentadienyl) and sodium diallryl-dithiocarbamates
under inert atmosphere. The bright green air-sensitive compounds are
paramagnetic with one unpaired electron per titanium atom. Their formulation as
monomeric, symmetrical bidentate chelate complexes
(See diagram in article)
has been established from
spectral, magnetic, and molecular weight data.
Cited by
21 articles.
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