Abstract
The synthesis, characterisation, and isolation of 1,1′,2-tribromoferrocene and 1,1′,2,2′-tetrabromoferrocene, which are key synthons in ferrocene chemistry, are described. These compounds are prepared using α-halide assisted lithiation. The crystal structures of 1,1′,2-tribromoferrocene, 1,1′,2,2′-tetrabromoferrocene, 1,1′-dibromoruthenocene, and 1,1′,2,2′-tetrabromoruthenocene have been determined and are reported together with a brief discussion of the intramolecular forces involved in the crystal structures.
Cited by
7 articles.
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1. 1,1′-Dibromo-2,2′,5,5′-tetrakis(methylthio)ferrocene;Molbank;2023-01-09
2. Isolation and crystal and molecular structures of [(C5H2Br3)2Fe], [(C5HBr4)2Fe] and [(C5Br5)(C5Br4HgBr)Fe];Acta Crystallographica Section C Structural Chemistry;2022-10-13
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5. Synthetic Route to 1,1′,2,2′-Tetraiodoferrocene That Avoids Isomerization and the Electrochemistry of Some Tetrahaloferrocenes;Organometallics;2021-07-23