Abstract
The Hammett acidity
function has been evaluated by means of spectrophotometric measurements with
thymol blue indicator for (1-x)(ZnCl2,RH2O)+x(LiCl,RH2O)
pseudobinary mixtures where R is 4 and 6. The pseudobinary mixtures have well
defined minimum acidity near the composition (x = 0.67) which corresponds to
the tetrachlorozincate ion stoichiometry. The acidity data for these mixtures
support the conclusion that the properties of mixtures with R ≤ 6 are
dominated by formation of tetrachlorozincate anions.
Cited by
2 articles.
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