Abstract
N-Alkylglucosylamines
and carbon disulphide react to give 3-alkyl-5-hydroxy- 5-(D-arabino-tetrahydroxybutyl)thiazolidine-2-thiones (I), which dehydrate to the
corresponding Δ4-thiazolines,
isolated only as tetraacetates. A
thiazolidine-2-thione forms also from the action of carbon disulphide on 1-N-methylamino-1-deoxy-D-fructose.
l-Bromo-l-deoxy-2,3:4,5-di-O-isopropylidene-D-fructose
is obtained by the action of dibromotriphenoxyphosphorane
on 2,3:4,5-di-O-isopropylidene-D-fructose.
Cited by
13 articles.
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