Author:
Forsyth Craig M.,Francis Craig L.,Jahangiri Saba,Liepa Andris J.,Perkins Michael V.,Young Anna P.
Abstract
N,N-dialkyl-N′-chlorosulfonyl chloroformamidines 1 reacted with 4-substituted urazoles 2 to give [1,2,4]triazolo[1,2-b][1,2,3,5]thiatriazoles 3 in a selective 1,2-NN dinucleophilic mode of reaction. The reaction of 1 with N
1-substituted pyrazol-5-ones 4 afforded pyrazolo[4,3-e][1,4,3]oxathiazines 5 via selective 1,3-CCO dinucleophilic substitution. Compounds 3 and 5 were the sole products isolated from the respective reactions and both represent new ring systems.
Cited by
9 articles.
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1. 1,2,3,5-Thiatriazoles;Comprehensive Heterocyclic Chemistry IV;2022
2. Dioxazines, Oxathiazines, and Dithiazines;Comprehensive Heterocyclic Chemistry IV;2022
3. New heteroatom-rich ring systems from N,N-dialkyl-N’-chlorosulfonyl chloroformamidines;Arkivoc;2016-06-06
4. Heterocyclization of N-(chlorosulfonyl)imidoyl chlorides with anilines, a new method of synthesis of 1,2,4-benzothiadiazine 1,1-dioxides;Chemistry of Heterocyclic Compounds;2016-04
5. Synthesis of Acyclic and Cyclic Sulfamates: A Review;Synthesis;2015-02-04