N,N-Dialkyl-N'-Chlorosulfonyl Chloroformamidines in Heterocyclic Synthesis. Part IX. Novel Triazolo-Fused Thiatriazoles and Pyrazolo-Fused Oxathiazines

Author:

Forsyth Craig M.,Francis Craig L.,Jahangiri Saba,Liepa Andris J.,Perkins Michael V.,Young Anna P.

Abstract

N,N-dialkyl-N′-chlorosulfonyl chloroformamidines 1 reacted with 4-substituted urazoles 2 to give [1,2,4]triazolo[1,2-b][1,2,3,5]thiatriazoles 3 in a selective 1,2-NN dinucleophilic mode of reaction. The reaction of 1 with N 1-substituted pyrazol-5-ones 4 afforded pyrazolo[4,3-e][1,4,3]oxathiazines 5 via selective 1,3-CCO dinucleophilic substitution. Compounds 3 and 5 were the sole products isolated from the respective reactions and both represent new ring systems.

Publisher

CSIRO Publishing

Subject

General Chemistry

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