Author:
Barton Richard H.,O'Connor Charmian J.
Abstract
The speciation of short-chain mixed acylglycerols in the product mix from
enzymatic hydrolysis has been examined by 13C n.m.r.
spectroscopy. Under conditions similar to those of the enzymatic reaction, but
in the absence of any enzyme, sample mixtures were allowed to stand in
buffered emulsions of known pH and temperature. There is clear evidence of
uncatalysed conversion of rac-1,2-diacylglycerol into
the 1,3-isomer to form an equilibrium mixture. Conversion kinetics to reach
equilibrium are first order and do not depend on the state of the emulsion.
Cited by
10 articles.
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