The Chemistry of Lauren-1-ene. XVII Preparation of Unsaturated Oxa and Aza Tetracycles.
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Published:1997
Issue:4
Volume:50
Page:279
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ISSN:0004-9425
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Container-title:Australian Journal of Chemistry
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language:en
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Short-container-title:Aust. J. Chem.
Author:
Chin Anna Fu Oi,Hanton Lyall R.,Weavers Rex T.
Abstract
Several lauren-1-ene-derived compounds containing an exocyclic methylene
grouping have been synthesized. These include substances with both regular and
rearranged carbon frameworks. The X-ray structure of a rearranged α-methylene
lactone shows that an earlier assignment of stereochemistry is incorrect and
that this compound has an exceptionally distorted C=C-C=O unit.
The methylene derivatives prepared have proved to have low cytoxicity.
Publisher
CSIRO Publishing
Subject
General Chemistry
Cited by
1 articles.
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1. Diterpenoids;Natural Product Reports;1999