Organophosphorus chemistry. III. Synthesis of 3-Ethoxy-2-phenyl-1,3-azaphosphininane 3-oxide-Reference-Cited by-同舟云学术

Organophosphorus chemistry. III. Synthesis of 3-Ethoxy-2-phenyl-1,3-azaphosphininane 3-oxide

Published:1984 Issue:1 Volume:37 Page:205
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Hewitt DG,Teese MW

Abstract

Treatment of ethyl (3-bromopropyl)phosphonochloridate with benzylmagnesium chloride gave ethyl (benzyl)(3-bromopropyl)phosphinate. This underwent free-radical bromination to give ethyl (a-bromobenzyl)(3-bromopropyl)phosphinate Cyclization with aqueous ammonia gave 3-ethoxy- 2-phenyl-1,3-azaphosphininane 3-oxide. Attempts to prepare the 2-(pyridin-3'-yl)-substituted 1,3-azaphosphininane are also discussed.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH9840205

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