Author:
Du Shuming,Zhang Jie,Guan Yan,Wan Xinhua
Abstract
Two poly(p-phenylene terephthalamide) (PPTA)-based macroinitiators with random and alternate sequences, i.e. poly(p-phenylene terephthalamide)-ran-poly[p-phenylene (2,2,6,6-tetramethylpiperidinyl-1-oxy)terephthalamide)] (CPPTA-ran) and poly(p-phenylene terephthalamide)-alt-poly[p-phenylene (2,2,6,6-tetramethylpiperidinyl-1-oxy)terephthalamide)] (CPPTA-alt), were prepared via copolycondensation of terephthaloyl chloride, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO)-functionalized terephthaloyl chloride, and p-phenylenediamine. The graft copolymers consisting of rigid PPTA backbones and polystyrene side chains were obtained by nitroxide-mediated radical polymerization. Both macroinitiators and graft copolymers were characterized by thermal gravimetric analysis, differential scanning calorimetry, wide-angle X-ray diffraction, and polarized optical microscopy. The regular incorporation of the TEMPO-containing co-unit gives rise to remarkable effects on the thermal stability, lyotropic liquid crystallinity, and macromolecular packing in bulk. CPPTA-alt shows better thermal stability and more ordered intermolecular structure than CPPTA-ran. The former generates a nematic phase at a concentration of 18 wt-% in concentrated sulfuric acid, whereas the latter does so at a concentration of 12 wt-%. For the graft copolymers, the alternative main chains exhibit sharper diffraction than the random ones. However, the sequence change exerts no discernible effect on other properties.
Cited by
16 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献