Abstract
Boron trichloride catalyses
the isomerization of cyclopropane into propene at 360-470�. The reaction is
first order in the pressure of each reactant, and the variation of rate with
temperature is given by the Arrhenius equation:
������������ k2 = 1011.35�0.2exp[(-106600
� 3100)/8.314T] s-1 ml mol-1
The reaction is believed to
be homogeneous and molecular. This is the first example of the series where the
catalyst has been a Lewis acid.
Cited by
13 articles.
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